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Metal state in high-temperature superconductors studied in more detail

8. November 2021
in News

Researchers at Chalmers Uni­ver­si­ty of Tech­nol­o­gy, Swe­den, have dis­cov­ered a strik­ing new behav­ior of the “strange met­al state” of high-tem­per­a­ture super­con­duc­tors. The dis­cov­ery is an impor­tant piece of the puz­zle for under­stand­ing these mate­ri­als. The find­ings were pub­lished in the pres­ti­gious jour­nal Science.

Super­con­duc­tiv­i­ty, in which elec­tric cur­rent is trans­port­ed with­out loss­es, holds enor­mous poten­tial for envi­ron­men­tal­ly friend­ly tech­nolo­gies. For exam­ple, if it works at suf­fi­cient­ly high tem­per­a­tures, it could enable the loss­less trans­port of renew­able ener­gy over long dis­tances. Study­ing this phe­nom­e­non is the goal of the research field of high-tem­per­a­ture super­con­duc­tiv­i­ty. The cur­rent record is ‑130 degrees Cel­sius, which may not seem like a high tem­per­a­ture, but it is a high tem­per­a­ture com­pared to stan­dard super­con­duc­tors, which only work at tem­per­a­tures below ‑230 degrees Cel­sius. While stan­dard super­con­duc­tiv­i­ty is well under­stood, var­i­ous aspects of high-tem­per­a­ture super­con­duc­tiv­i­ty are still a mys­tery to be solved. The new­ly pub­lished research focus­es on the least explored prop­er­ty — the so-called “strange met­al” state that occurs at tem­per­a­tures high­er than those that enable superconductivity.

“This ‘strange met­al’ state is apt­ly named. The mate­ri­als real­ly behave in a very unusu­al way, and it’s a mys­tery to researchers. Our work now offers a new under­stand­ing of the phe­nom­e­non. Through nov­el exper­i­ments, we have gained cru­cial new infor­ma­tion about how the strange met­al state works.”

- Flo­ri­ana Lom­bar­di, pro­fes­sor at the Lab­o­ra­to­ry for Quan­tum Physics

Presumably it is based on quantum entanglement

The strange met­al state got its name because its behav­ior in con­duct­ing elec­tric­i­ty is, at first glance, far too sim­ple. In an ordi­nary met­al, many dif­fer­ent process­es affect the elec­tri­cal resis­tance — elec­trons can col­lide with the atom­ic lat­tice, with impu­ri­ties, or with them­selves, and each process has a dif­fer­ent tem­per­a­ture depen­dence. This means that the result­ing total resis­tance is a com­pli­cat­ed func­tion of tem­per­a­ture. In stark con­trast, resis­tance in for­eign met­als is a lin­ear func­tion of tem­per­a­ture, mean­ing a straight line from the low­est tem­per­a­tures achiev­able to the point where the mate­r­i­al melts.

“Such sim­ple behav­ior calls for a sim­ple expla­na­tion based on a pow­er­ful prin­ci­ple, and for this type of quan­tum mate­r­i­al, the prin­ci­ple is believed to be quan­tum entan­gle­ment,” says Ulf Gran, a pro­fes­sor in the Depart­ment of Sub­atom­ic, High Ener­gy and Plas­ma Physics at Chalmers’ Fac­ul­ty of Physics.

“Quan­tum entan­gle­ment is what Ein­stein called ‘spooky action at a dis­tance’ and rep­re­sents a way for elec­trons to inter­act with each oth­er that has no equiv­a­lent in clas­si­cal physics. To explain the coun­ter­in­tu­itive prop­er­ties of the strange metal­lic state, all par­ti­cles must be entan­gled with each oth­er, result­ing in a soup of elec­trons in which indi­vid­ual par­ti­cles are unde­tectable and which rep­re­sents a rad­i­cal­ly new form of matter.”

Exploring the connection with charge density waves

The most impor­tant result of the work is that the authors have fig­ured out what accounts for the strange met­al state. Charge den­si­ty waves (CDW) occur in high-tem­per­a­ture super­con­duc­tors, which are waves of elec­tric charge gen­er­at­ed by pat­terns of elec­trons in the mate­r­i­al lat­tice when the strange met­al phase col­laps­es. To inves­ti­gate this rela­tion­ship, nanoscale sam­ples of the super­con­duct­ing met­al yttri­um-bar­i­um-cop­per oxide were placed under volt­age to sup­press the charge den­si­ty waves. This then led to the reap­pear­ance of the strange met­al state. By stretch­ing the met­al, the researchers were able to extend the strange met­al state into the region pre­vi­ous­ly dom­i­nat­ed by the CDW — mak­ing the “strange met­al” even stranger.

“The high­est tem­per­a­tures for the super­con­duct­ing tran­si­tion were observed when the strange met­al phase was more pro­nounced. Under­stand­ing this new phase of mat­ter is there­fore of utmost impor­tance to be able to design new mate­ri­als that are super­con­duct­ing at even high­er tem­per­a­tures,” Flo­ri­ana Lom­bar­di explains.

The researchers’ work sug­gests a close con­nec­tion between the appear­ance of charge den­si­ty waves and the break­ing of the strange met­al state — a poten­tial­ly cru­cial clue to under­stand­ing the lat­ter phe­nom­e­non, which could rep­re­sent one of the most impres­sive proofs of quan­tum mechan­i­cal prin­ci­ples at the macro scale.

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